Molecular weight effects on chain pull-out fracture of reinforced polymeric interfaces

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Molecular weight effects on chain pull-out fracture of reinforced polymeric interfaces.

Using Brownian dynamics, we simulate the fracture of polymer interfaces reinforced by diblock connector chains. We consider the mushroom regime, where connector chains are grafted with low surface density, for the case of large pulling velocities. We find that for short chains the interface fracture toughness depends linearly on the degree of polymerization N of the connector chains, while for ...

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ژورنال

عنوان ژورنال: Physical Review E

سال: 1999

ISSN: 1063-651X,1095-3787

DOI: 10.1103/physreve.60.4460